Direct / line of sight
Common on VHF and UHF. Signals generally travel in straight paths, so hills, buildings and antenna height can make a dramatic difference.
Propagation
Radio waves do not all travel the same way. Frequency, time of day, the Sun, the ionosphere, terrain, weather and antenna angle can turn the same station from “not a whisper” to “full scale” without anyone touching the transmitter.
At VHF and UHF, many everyday contacts behave mostly like line-of-sight communication: antenna height and terrain matter a lot. At HF, radio waves can be refracted by the ionosphere and return to Earth hundreds or thousands of miles away. That is how a modest station and a wire antenna can sometimes make contacts across continents.
The important beginner idea is simple: the band that works best can change with distance, time, season and solar conditions. Good operators learn to ask “what path is likely open right now?” instead of assuming more power is always the answer.
The big paths
Common on VHF and UHF. Signals generally travel in straight paths, so hills, buildings and antenna height can make a dramatic difference.
Some lower-frequency energy follows the Earth’s surface. It matters more at lower frequencies and is not the main reason most hams work worldwide DX.
HF signals can be bent back toward Earth by ionized regions high in the atmosphere, making long-distance contacts possible well beyond the horizon.
Temporary patches of intense ionization in the E region can produce surprising openings—often on 6 meters and sometimes higher—where stations suddenly appear from far beyond normal range.
Temperature and moisture structures in the lower atmosphere can bend VHF/UHF signals and extend their range. Ducting can produce unexpectedly long contacts over land or water.
Hams can use ionized meteor trails or auroral ionization to make contacts that ordinary line-of-sight propagation would not support.
The Sun changes the bands
Solar ultraviolet radiation helps create ionization. Solar flares, geomagnetic disturbances and the roughly 11-year solar cycle can improve some paths and disrupt others.
Some ionospheric layers strengthen in daylight and weaken after sunset. That is one reason a band can behave very differently at 2 PM and 2 AM.
Higher HF bands often benefit from stronger ionization and daylight, while lower HF bands can become excellent after dark as absorption decreases.
More solar activity can support exciting higher-frequency HF openings, but strong solar events can also disturb the ionosphere and temporarily hurt communications.
Propagation tools can estimate what should work, but the ionosphere keeps enough personality to make listening and experimenting worthwhile.
Try thinking like an operator
Where this goes next
Good outside references: ARRL Propagation of RF Signals and ARRL propagation resources.